Atomization Mechanism of Silver Deposited on Pyrolyzed Ascorbic Acid in Graphite Furnace Atomic Absorption Spectrometry
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چکیده
منابع مشابه
GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY WITH MAlIlRIX MODIFICATION FOR DETERMINATION OF LEAD IN DRINKING WATER
An amoniumvanadate plus sodium molybdate mixed modifier Graphite Furnace Atomic Absorption Spectrometric method has been developed for determination of traces of lead in drinking water. The concentration of lead in the sample is obtained by direct comparison to linear working graph prepared from aqueous standards in the modifier medium, The results indicate the better performance of the pro...
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In this work a rapid and selective procedure for separation and preconcentration of lead(Pb2+) before determination by electrothermal atomic absorption spectrometry (ETAAS) wasdeveloped. The procedure is based on the electrodeposition on a graphite probe modified withpalladium. The lead was deposited from acetate buffer solution at pH 5.5. Various parameters,such as pH of solutions, deposition ...
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an amoniumvanadate plus sodium molybdate mixed modifier graphite furnace atomic absorption spectrometric method has been developed for determination of traces of lead in drinking water. the concentration of lead in the sample is obtained by direct comparison to linear working graph prepared from aqueous standards in the modifier medium, the results indicate the better performance of the propose...
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The sensitivity of graphite furnace atomic absorption spectrometry (GFAAS) to arsenobetaine (AB) was 1.3-times higher than to inorganic As. In order to understand the mechanism underlying this observation, the atomization processes for both chemical species were investigated in terms of the enthalpy change (DeltaH) during the atomization process in GFAAS. The enthalpy change of AB was slightly ...
متن کاملdirect determination of arsenic in potassium citrate tablet using graphite furnace atomic absorption spectrometry
in this study, a rapid and simple method based on graphite furnace atomic absorption spectrometry (gfaas) is described for direct determination of arsenic in potassium citrate tablet samples. pyrolytic graphite tubes were used as atomizers. nickel nitrate was used as chemical modifier. the ashing and atomization temperature and the concentration of modifier were also optimized. the detection li...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 2005
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.54.621